Insecticides

An insecticide is a pesticide used against insects in all developmental forms. They include ovicides and larvicides used against the eggs and larvae of insects respectively. Insecticides are used in agriculture, medicine, industry and the household. The use of insecticides is believed to be one of the major factors behind the increase in agricultural productivity in the 20th century. Nearly all insecticides have the potential to significantly alter ecosystems; many are toxic to humans; and others are concentrated in the food chain. It is necessary to balance agricultural needs with environmental and health issues when using insecticides.

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Classes of agricultural insecticides
The classification of insecticides is done in several different ways:

Systemic insecticides are incorporated by treated plants. Insects ingest the insecticide while feeding on the plants.
Contact insecticides are toxic to insects brought into direct contact. Efficacy is often related to the quality of pesticide application, with small droplets (such as aerosols) often improving performance.
Natural insecticides, such as nicotine and pyrethrum, are made by plants as defences against insects. Nicotine based insecticides have been barred in the U.S. since 2001 to prevent residues from contaminating foods.
Inorganic insecticides are manufactured with metals and include arsenates copper- and fluorine compounds, which are now seldom used, and sulfur, which is commonly used.
Organic insecticides are synthetic chemicals which comprise the largest numbers of pesticides available for use today.
Mode of action – how the pesticide kills or inactivates a pest – is another way of classifying insecticides. Mode of action is important in predicting whether an insecticide will be toxic to unrelated species such as fish, birds and mammals.
Heavy metals, e.g. lead, mercury, arsenic, as well as plant toxins such as nicotine have been used for many years. Various plants have been used as folk insecticides for centuries, including tobacco and pyrethrum. Some farmers are reporting successfully using spray of crudely fermented alcohol as an effective insecticide.

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Organochlorine compounds
The insectcidal properties of the best known representative of this class of insecticides, DDT, was made by the Swiss Scientist Paul Műller. For this discovery, he was awarded the Nobel Prize for Physiology and Medicine in 1948. DDT was introduced on the market in 1944. With the rise of the modern chemical industry it was possible to make chlorinated hydrocarbons. DDT works by opening the sodium channels in the nerve cells of the insect.


Organophosphates
The next large class developed was the organophosphates, which bind to acetylcholinesterase and other cholinesterases. This results in disruption of nervous impulses, killing the insect or interfering with its ability to carry on normal functions. Organophosphate insecticides and chemical warfare nerve agents (such as sarin, tabun, soman and VX) work in the same way. Organophosphates have an additive toxic effect to wildlife, so multiple exposures to the chemicals amplifies the toxicity.

Carbamate insecticides have similar toxic mechanisms but have a much shorter duration of action and are thus somewhat less toxic.


Pyrethroids
To mimic the insecticidal activity of the natural compound pyrethrum another class of pesticides, pyrethroid pesticides, have been developed. These are nonpersistent and much less acutely toxic than organophosphates and carbamates.


Neonicotinoids
Neonicotinoids are synthetic analogues of the natural insecticide nicotine (with a much lower acute mammalian toxicity and greater field persistence). Broad-spectrum – systemic insecticides with a rapid action (minutes-hours). They are applied as sprays, drenches, seed and soil treatments - often as substitutes for organophosphates and carbamates. Treated insects exhibit leg tremors, rapid wing motion, stylet withdrawal (aphids), disorientated movement, paralysis and death.


Biological insecticides
Recent efforts to reduce broad spectrum toxins added to the environment have brought biological insecticides back into vogue. An example is the development and increase in use of Bacillus thuringiensis, a bacterial disease of Lepidopterans and some other insects. It is used as a larvicide against a wide variety of caterpillars. Because it has little effect on other organisms, it is considered more environmentally friendly than synthetic pesticides. The toxin from B. thuringiensis (Bt toxin) has been incorporated directly into plants through the use of genetic engineering. Other biological insecticides include products based on entomopathogenic fungi (e.g. Metarhizium anisopliae), nematodes (e.g. Steinernema feltiae) and viruses (e.g. Cydia pomonella granulovirus).


Environmental effects

Effects on nontarget species
Some insecticides kill or harm other creatures in addition to those they are intended to kill. For example, birds may be poisoned when they eat food that was recently sprayed with insecticides or when they mistake insecticide granules on the ground for food and eat it.

Sprayed insecticides may drift from the area to which it is applied and into wildlife areas, especially when it is sprayed aerially.


DDT
Main article: DDT
One of the bigger drivers in the development of new insecticides has been the desire to replace toxic and irksome insecticides. DDT was introduced as a safer alternative to the lead and arsenic compounds. It is the case that when used under the correct conditions that almost any chemical substance is 'safe', but when used under the wrong conditions most insecticides can be a threat to health and/or the environment.

Some insecticides have been banned due to the fact that they are persistent toxins which have adverse effects on animals and/or humans. An oft-quoted case is that of DDT, an example of a widely used (and maybe misused) pesticide, which was brought to public attention by Rachel Carson's book, Silent Spring. One of the better known impacts of DDT is to reduce the thickness of the egg shells on predatory birds. The shells sometimes become too thin to be viable, causing reductions in bird populations. This occurs with DDT and a number of related compounds due to the process of bioaccumulation, wherein the chemical, due to its stability and fat solubility, accumulates in organisms' fatty tissues. Also, DDT may biomagnify which causes progressively higher concentrations in the body fat of animals farther up the food chain. The near-worldwide ban on agricultural use of DDT and related chemicals has allowed some of these birds—such as the peregrine falcon--to recover in recent years. A number of the organochlorine pesticides have been banned from most uses worldwide and globally they are controlled via the Stockholm Convention on persistent organic pollutants. These include: aldrin, chlordane, DDT, dieldrin, endrin, heptachlor, mirex and toxaphene.


Pollinator decline
Insecticides can kill bees and may be a cause of pollinator decline, the loss of species that pollinate plants, including through the mechanism of Colony Collapse Disorder, in which worker bees from a beehive or Western honey bee colony abruptly disappear. Loss of pollinators will mean a reduction in crop yields.

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Application methods for household insecticides
Integrated pest management or IPM in the home begins with restricting the availability to insects of three vital commodities: shelter, water and food. If insects become a problem despite such measures, IPM seeks to control them using the safest possible methods, targeting the approach to the particular pest.

Insect repellent, referred to as "bug spray", comes in a plastic bottle or aerosol can. Applied to clothing, arms, legs, and other extremities, the use of these products will tend to ward off nearby insects. This is not an insecticide.

Insecticide used for killing pests—most often insects, and arachnids—primarily comes in an aerosol can, and is sprayed into the air or a nest as a means of killing the animal. Fly sprays will kill house flies, blowflies, ants, cockroaches and other insects and also spiders. Other preparations are granules or liquids that are formulated with bait that is eaten by insects. For many household pests bait traps are available that contain the pesticide and either pheromone or food baits. Crack and crevice sprays are applied into and around openings in houses such as baseboards and plumbing. Pesticides to control termites are often injected into and around the foundations of homes.

Active ingredients of many household insecticides include permethrin and tetramethrin, which act on the nervous system of insects and arachnids.

Bug sprays should be used in well ventilated areas only, as the chemicals contained in the aerosol and most insecticides can be harmful or deadly to humans and pets. All insecticide products including solids, baits and bait traps should be applied such that they are out of reach of wildlife, pets and children.

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Individual insecticides

Chlorinated hydrocarbons
See also: Category:Organochloride insecticides
Aldrin
Chlordane
Chlordecone
DDT
Dieldrin
Endosulfan
Endrin
Heptachlor
Hexachlorobenzene
Lindane (gamma-Hexachlorocyclohexane)
Methoxychlor
Mirex
Pentachlorophenol
TDE

Organophosphates
Acephate
Azinphos-methyl
Bensulide
Chlorethoxyfos
Chlorpyrifos
Chlorpyriphos-methyl
Diazinon
Dichlorvos (DDVP)
Dicrotophos
Dimethoate
Disulfoton
Ethoprop
Fenamiphos
Fenitrothion
Fenthion
Fosthiazate
Malathion
Methamidophos
Methidathion
Mevinphos
Naled
Omethoate
Oxydemeton-methyl
Parathion
Parathion-methyl
Phorate
Phosalone
Phosmet
Phostebupirim
Phoxim
Pirimiphos-methyl
Profenofos
Philayosfon
Terbufos
Tetrachlorvinphos
Tribufos
Trichlorfon

Carbamates
Aldicarb
Carbofuran
Carbaryl
Methomyl
2-(1-Methylpropyl)phenyl methylcarbamate

Phenothiazine

Pyrethroids
Allethrin
Bifenthrin
Cypermethrin
Deltamethrin
Lambda-cyhalothrin
Permethrin
Resmethrin
Tetramethrin
Tralomethrin
Transfluthrin

Neonicotinoids
Acetamiprid
Clothianidin
Imidacloprid
Nitenpyram
Nithiazine
Thiacloprid
Thiamethoxam

Plant derived
Caffeine
Derris (rotenone)
Anabasine
Anethole (mosquito larvae)
Annonin
Asimina (Pawpaw tree seeds) for lice
Azadirachtin
Carapa
Cinnamon leaf oil (very effective for killing mosquito larvae)
Cinnamaldehyde (very effective for killing mosquito larvae)
Cinnamyl acetate (kills mosquito larvae)
Deguelin
Derris
Desmodium caudatum (leaves and roots)
Eugenol (mosquito larvae)
Linalool
Myristicin
Neem (Azadirachtin)
Nicotiana rustica (Nicotine)
Peganum harmala, seeds (smoke from), root
Oregano oil kills beetles Rhizoppertha dominica (bug found in stored cereal)
Polyketide
Pyrethrum
Quassia (South American plant genus)
Tetranortriterpenoid
Thymol (controls varroa mites in bee colonies)


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